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Whether the M.2 slot on your PC supports NVMe depends on the motherboard. If both the motherboard and SSD support NVMe, you should enable NVMe/PCIe mode in the BIOS.

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Removable 2 Bay M.2 NVMe SSD to PCIe 4.0 x8 Mobile Rack Enclosure for PCI Express Slot (PCIe Bifurcation required) ... Note: To utilize an M.2, U.2, or U.3 NVMe SSD in a PCIe 16x slot, the motherboard or add-on card must support PCIe Bifurcation.